Electrochemical Aziridination by Alkene Activation Using a Sulfamate as the Nitrogen Source. (20th April 2018)
- Record Type:
- Journal Article
- Title:
- Electrochemical Aziridination by Alkene Activation Using a Sulfamate as the Nitrogen Source. (20th April 2018)
- Main Title:
- Electrochemical Aziridination by Alkene Activation Using a Sulfamate as the Nitrogen Source
- Authors:
- Li, Jin
Huang, Wenhao
Chen, Jingzhi
He, Lingfeng
Cheng, Xu
Li, Guigen - Abstract:
- Abstract: The first direct aziridination of triaryl‐substituted alkenes was achieved by means of an electrochemical process that could extend to multisubstituted styrenes. Specifically, hexafluoroisopropanol sulfamate was used as a nucleophilic nitrogen source. Mechanistic experiments suggest that this electrochemical process proceeds by stepwise formation of two C−N bonds through reactions between cationic carbon species and the sulfamate.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 20(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 20(2018)
- Issue Display:
- Volume 130, Issue 20 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 20
- Issue Sort Value:
- 2018-0130-0020-0000
- Page Start:
- 5797
- Page End:
- 5800
- Publication Date:
- 2018-04-20
- Subjects:
- Alkene -- Aziridine -- Elektrochemie -- Radikale -- Synthesemethoden
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201801106 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 10782.xml