Shell‐Isolated Tip‐Enhanced Raman and Fluorescence Spectroscopy. Issue 25 (26th April 2018)

• Record Type: Journal Article
• Authors: Huang, Ya‐Ping; Huang, Sheng‐Chao; Wang, Xiang‐Jie; Bodappa, Nataraju; Li, Chao‐Yu; Yin, Hao; Su, Hai‐Sheng; Meng, Meng; Zhang, Hua; Ren, Bin; Yang, Zhi‐Lin; Zenobi, Renato; Tian, Zhong‐Qun; Li, Jian‐Feng
• Is Part Of: Angewandte Chemie international edition. Volume 57:Issue 25(2018)
• Page Start: 7523
• Page End: 7527
• Publication Date: 2018-04-26
• Subjects: atomic layer deposition -- fluorescence -- Raman spectroscopy -- shell-isolated tip -- tip-enhanced Raman spectroscopy; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201802892
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Tip‐enhanced Raman spectroscopy can provide molecular fingerprint information with ultrahigh spatial resolution, but the tip will be easily contaminated, thus leading to artifacts. It also remains a great challenge to establish tip‐enhanced fluorescence because of the quenching resulting from the proximity of the metal tip. Herein, we report shell‐isolated tip‐enhanced Raman and fluorescence spectroscopies by employing ultrathin shell‐isolated tips fabricated by atomic layer deposition. Such shell‐isolated tips not only show outstanding electromagnetic field enhancement in TERS but also exclude interference by contaminants, thus greatly promoting applications in solution. Tip‐enhanced fluorescence has also been achieved using these shell‐isolated tips, with enhancement factors of up to 1.7×10 3, consistent with theoretical simulations. Furthermore, tip‐enhanced Raman and fluorescence signals are acquired simultaneously, and their relative intensities can be manipulated by changing the shell thickness. This work opens a new avenue for ultrahigh resolution surface analysis using plasmon‐enhanced spectroscopies. Abstract : Combined tip‐enhanced Raman and fluorescence spectroscopy using shell‐isolate tips is presented. With this method, clear and strong Raman and fluorescence signals can be obtained, and their relative intensities can be tuned by changing the shell thickness.