Classifying Degraded Modern Polymeric Museum Artefacts by Their Smell. (2nd March 2018)

• Record Type: Journal Article
• Authors: Curran, Katherine; Underhill, Mark; Grau‐Bové, Josep; Fearn, Tom; Gibson, Lorraine T.; Strlič, Matija
• Is Part Of: Angewandte Chemie. Volume 130:Number 25(2018)
• Page Start: 7458
• Page End: 7462
• Publication Date: 2018-03-02
• Subjects: Flüchtige organische Verbindungen -- Gaschromatographie -- Kulturgüter -- Massenspektrometrie -- Plastikkonservierung; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201712278
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: The use of VOC analysis to diagnose degradation in modern polymeric museum artefacts is reported. Volatile organic compound (VOC) analysis is a successful method for diagnosing medical conditions but to date has found little application in museums. Modern polymers are increasingly found in museum collections but pose serious conservation difficulties owing to unstable and widely varying formulations. Solid‐phase microextraction gas chromatography/mass spectrometry and linear discriminant analysis were used to classify samples according to the length of time they had been artificially degraded. Accuracies in classification of 50–83 % were obtained after validation with separate test sets. The method was applied to three artefacts from collections at Tate to detect evidence of degradation. This approach could be used for any material in heritage collections and more widely in the field of polymer degradation.