Zinc terephthalates ZnC8H4O4 as anodes for lithium ion batteries. (1st May 2017)

• Record Type: Journal Article
• Authors: Wang, Liping; Zou, Jian; Chen, Shulin; Yang, Jingyi; Qing, Fangzhu; Gao, Peng; Li, Jingze
• Is Part Of: Electrochimica acta. Volume 235(2017)
• Page Start: 304
• Page End: 310
• Publication Date: 2017-05-01
• Subjects: Amorphous -- Carbonyl compounds -- Organic electrodes -- Zinc terephthalate -- Metal organic framework; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2017.03.095
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: Both of well-crystalline and amorphous zinc terephthalates ZnC8 H4 O4 are synthesized and amorphous structure demonstrates a higher capacity and better cycling performance. Highlights: Crystalline and amorphous ZnC8 H4 O4 are obtained. Both crystalline and amorphous ZnC8 H4 O4 have σe of 10 −7 S m −1 . Lithium ion diffusion is the rate-determine process. Amorphous has a high capacity and durable performance. Amorphous ZnC8 H4 O4 has a high apparent lithium ion diffusion coefficient. Abstract: Organic materials offer the advantages of cost-effective, environmental benignity, and molecular structural diversity as applications of electrode materials for lithium ion batteries. In fact, their lithium storage behaviors in terms of dynamics and kinetics intrinsically lie in ion migration in solids. Thus the solid forms including crystalline and amorphous states are crucial for the properties. In this study, a conventional carbonyl type organic material, namely zinc terephthalate (ZnC8 H4 O4 ), is obtained in both well-crystalline and amorphous forms and applied as anodes for lithium ion batteries. ZnC8 H4 O4 with amorphous structure shows higher lithium storage capacity and better capacity retention compared with that of crystalline one. It is ascribed that the amorphous phase provides a higher lithium ion diffusion coefficient than the crystalline one under the conditions of similar electronic conductivity.