Removal of Zn (II) and Cu (II) Ions from Industrial Wastewaters Using Magnetic Biochar Derived from Water Hyacinth. (15th May 2019)

• Record Type: Journal Article
• Authors: Nyamunda, Benias C.; Chivhanga, Terrence; Guyo, Upenyu; Chigondo, Fidelis
• Other Names: Sun Runcang Academic Editor.
• Is Part Of: Journal of engineering. Volume 2019(2019)
• Publication Date: 2019-05-15
• Subjects: Engineering -- Periodicals; 620.005
• DOI: 10.1155/2019/5656983
• Languages: English
• ISSNs: 2314-4904

Abstract

Abstract : This study evaluates the effectiveness of magnetic biochar (Fe2 O3 -EC) derived from water hyacinth in the removal of Cu +2 and Zn +2 from aqueous solution. Fe2 O3 -EC was prepared by chemical coprecipitation of a mixture of FeCl2 and FeCl3 on water hyacinth biomass followed by pyrolysis. The adsorbent was characterized by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDX). Batch adsorption studies on the effects of temperature, biosorbent dosage, contact time, and initial metal ion concentration were carried out. Fe2 O3 -EC exhibited optimum contact time, biosorbent dosage, and pH values of 65 min, 1.2 g, and 6, respectively. Fe2 O3 -EC exhibited strong magnetic separation ability and high sorption capability. Metal ion adsorption onto the biochar conformed to the Langmuir isotherm. Kinetic studies revealed that the adsorption process followed pseudo-second-order model. The calculated thermodynamic parameters showed that the adsorption process was feasible and exothermic in nature. These results have demonstrated that the use of Fe2 O3 -EC in metal ion removal could provide an alternative way to manage and utilize this highly problematic invasive species.