Conductive carbon nanosheets prepared from brominated polystyrene through ion beam irradiation and carbonization. (June 2019)

• Record Type: Journal Article
• Authors: Kim, Seung-Woo; Jung, Chan-Hee; Kwon, Sung-Nam; Na, Seok-In
• Is Part Of: Radiation physics and chemistry. Volume 159(2019:Jun.)
• Page Start: 6
• Page End: 11
• Publication Date: 2019-06
• Subjects: Carbon nanosheet -- Graphene-like structure -- Polystyrene -- Ion-beam irradiation -- Transparent electrode -- Polymeric photovoltaics; Radiation chemistry -- Periodicals; Radiometry -- Periodicals; Radiation -- Periodicals; Chimie sous rayonnement -- Périodiques; 539.2
• DOI: 10.1016/j.radphyschem.2019.02.032
• Languages: English
• ISSNs: 0969-806X

Abstract

Abstract: We fabricated a conductive carbon nanosheet (CNS) film converted from brominated polystyrene (PS) and demonstrated that the CNS film can act as transparent electrode (TE) for polymeric photovoltaics (PPVs). The PS-converted CNS film was fabricated simply with spin-coating of a cost-effective PS solution, followed by stabilization via ion-beam irradiation and carbonization via heat treatment to convert PS to CNS. The analytical results revealed that the PS film was successfully stabilized by ion-beam irradiation and the conductive CNS with graphene-like structure was synthesized. The PPVs with the PS-converted CNS as a TE showed a feasible power conversion efficiency of ~0.61% under a standard 1 sun condition, thus, confirming that the ion-beam based CNS-formation approach and the PS-converted CNS can be useful in transparent electrode applications. Highlights: Conductive carbon nanosheet (CNS) films were fabricatd from polystyrene (PS). The PS film was effectively stabilized by the ion-beam and converted to CNS by the carbonization process. The PS-converted CNS served as a transparent electrode for polymeric photovoltaics.