Cover Feature: Synthesis and Electronic Properties of Triperyleno[3.3.3]Propellanes: Towards Two‐Dimensional Electronic Structures (ChemPlusChem 6/2019). Issue 6 (2nd May 2019)

• Record Type: Journal Article
• Authors: Kodama, Takuya; Miyazaki, Shogo; Kubo, Takashi
• Is Part Of: ChemPlusChem. Volume 84:Issue 6(2019)
• Page Start: 560
• Page End: 560
• Publication Date: 2019-05-02
• Subjects: arenes -- homoconjugation -- perylene -- radical cations -- through-space interactions; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cplu.201900240
• Languages: English
• ISSNs: 2192-6506

Abstract

Abstract : The cover feature shows a two‐dimensional honeycomb‐like network formed by the self‐assembly of triperyleno[3.3.3]propellane (TPRP), which is composed of three perylene units peri ‐fused on [3.3.3]propellane. TPRP shows a bathochromic‐shifted absorption band, three well‐separated redox waves, and spin delocalization among the perylene blades, thus indicating a homoconjugative interaction between the π‐blades. Details are given in the Communication by T. Kubo and co‐workers onpage 599 in Issue 6, 2019 (DOI:10.1002/cplu.201800614 ).