Anti‐Oxygen Leaking LiCoO2. (5th April 2019)

• Record Type: Journal Article
• Authors: Sharifi‐Asl, Soroosh; Soto, Fernando A.; Foroozan, Tara; Asadi, Mohammad; Yuan, Yifei; Deivanayagam, Ramasubramonian; Rojaee, Ramin; Song, Boao; Bi, Xuanxuan; Amine, Khalil; Lu, Jun; Salehi‐khojin, Amin; Balbuena, Perla B.; Shahbazian‐Yassar, Reza
• Is Part Of: Advanced functional materials. Volume 29:Number 23(2019)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-04-05
• Subjects: cathode surface design -- DFT/AIMD modeling -- graphene‐coating -- in situ TEM -- LiCoO2 oxygen release -- thermal degradation; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201901110
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: LiCoO2 is a prime example of widely used cathodes that suffer from the structural/thermal instability issues that lead to the release of their lattice oxygen under nonequilibrium conditions and safety concerns in Li‐ion batteries. Here, it is shown that an atomically thin layer of reduced graphene oxide can suppress oxygen release from Li x CoO2 particles and improve their structural stability. Electrochemical cycling, differential electrochemical mass spectroscopy, differential scanning calorimetry, and in situ heating transmission electron microscopy are performed to characterize the effectiveness of the graphene‐coating on the abusive tolerance of Li x CoO2 . Electrochemical cycling mass spectroscopy results suggest that oxygen release is hindered at high cutoff voltage cycling when the cathode is coated with reduced graphene oxide. Thermal analysis, in situ heating transmission electron microscopy, and electron energy loss spectroscopy results show that the reduction of Co species from the graphene‐coated samples is delayed when compared with bare cathodes. Finally, density functional theory and ab initio molecular dynamics calculations show that the rGO layers could suppress O2 formation more effectively due to the strong COcathode bond formation at the interface of rGO/LCO where low coordination oxygens exist. This investigation uncovers a reliable approach for hindering the oxygen release reaction and improving the thermal stability of battery cathodes. Abstract : An atomically thin layer of reduced graphene oxide is reported to have the ability to suppress oxygen release from LiCoO2 particles. The DFT/AIMD simulations show that the presence of rGO increases the energy barrier for O2 formation and hinders further O2 release from LiCoO2 . The rGO‐coating also impedes the degradation of LiCoO2, which is evidenced through electrochemical measurements.