Bond theory, terahertz spectra, and dielectric studies in donor‐acceptor (Nb‐Al) substituted ZnTiNb2O8 system. Issue 8 (28th January 2019)

• Record Type: Journal Article
• Authors: Luo, Weijia; Li, Lingxia; Yu, Shihui; Li, Jining; Zhang, Bowen; Qiao, Jianli; Chen, Siliang
• Is Part Of: Journal of the American Ceramic Society. Volume 102:Issue 8(2019)
• Page Start: 4612
• Page End: 4620
• Publication Date: 2019-01-28
• Subjects: complex chemical bond theory -- covalency -- dielectric properties -- donor‐acceptor substituted -- microwave and terahertz; Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.16318
• Languages: English
• ISSNs: 0002-7820

Abstract

Abstract: As a donor and acceptor separately, Nb 5+ and Al 3+ are used to substitute Ti 4+ in the ixiolite ZnTiNb2 O8 system for the first time. The dielectric responses in the terahertz range of this system are initially studied based on the data from terahertz time‐domain transmitted spectroscopy. Combined with ligand field theory, the formation of a secondary phase of ZnAl2 O4 is reasonably explicated. Then, the origins of the lower dielectric loss and the terahertz wave absorption coefficient are determined to be the high chemical bond covalency and effective phase control. For the composition of ZnTi0.85 (Al0.5 Nb0.5 )0.15 Nb2 O8 sintered at 1180°C, a low dielectric loss (<5 × 10 −3 @ 0.5 THz) and absorption coefficient (<10/cm @ 0.5 THz) are obtained, which make this kind of material propitious for developing terahertz dielectric devices.