A Reusable Cobalt Catalyst for Reversible Acceptorless Dehydrogenation and Hydrogenation of N‐Heterocycles. Issue 10 (29th April 2019)

• Record Type: Journal Article
• Authors: Jaiswal, Garima; Subaramanian, Murugan; Sahoo, Manoj K.; Balaraman, Ekambaram
• Is Part Of: ChemCatChem. Volume 11:Issue 10(2019)
• Page Start: 2449
• Page End: 2457
• Publication Date: 2019-04-29
• Subjects: Cobalt catalyst -- N-heterocycles -- Acceptorless dehydrogenation -- Hydrogenation -- Heterogeneous catalysis; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201900367
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract: The development of robust catalytic systems based on base‐metals for reversible acceptorless dehydrogenation (ADH) and hydrogenation of feedstock chemicals is very important in the context of 'hydrogen storage'. Herein, we report a highly efficient reusable cobalt‐based heterogeneous catalyst for reversible dehydrogenation and hydrogenation of N‐heterocycles. Both the ADH and the hydrogenation processes operate under mild, benign conditions. Abstract : Simple, efficient and mild : An efficient reusable cobalt‐based heterogeneous catalyst for reversible dehydrogenation and hydrogenation of N‐heterocycles is reported. Both processes are catalyzed by a single reusable cobalt‐catalyst that operates under mild and benign conditions.