Simple and scalable synthesis of the carborane anion CB11H12−. Issue 22 (26th March 2019)
- Record Type:
- Journal Article
- Title:
- Simple and scalable synthesis of the carborane anion CB11H12−. Issue 22 (26th March 2019)
- Main Title:
- Simple and scalable synthesis of the carborane anion CB11H12−
- Authors:
- Toom, Lauri
Kütt, Agnes
Leito, Ivo - Abstract:
- Abstract : Simple and easily scalable preparation of the useful carborane anion CB11 H12 − is reported using a boron cluster B11 H14 − and CF3 SiMe3 . Abstract : We report a method to obtain carba- closo -dodecaborate anion CB11 H12 − from boron cluster B11 H14 − in up to 95% yield using difluorocarbene to complete the carborane cluster. Difluorocarbene itself comes from readily available Ruppert–Prakash reagent CF3 SiMe3 . The synthesis is straightforward to carry out in heavy wall glass pressure tubes without the need for a glove-box and is easily scalable to 15 g scale.
- Is Part Of:
- Dalton transactions. Volume 48:Issue 22(2019)
- Journal:
- Dalton transactions
- Issue:
- Volume 48:Issue 22(2019)
- Issue Display:
- Volume 48, Issue 22 (2019)
- Year:
- 2019
- Volume:
- 48
- Issue:
- 22
- Issue Sort Value:
- 2019-0048-0022-0000
- Page Start:
- 7499
- Page End:
- 7502
- Publication Date:
- 2019-03-26
- Subjects:
- Chemistry, Inorganic -- Periodicals
Chemistry, Physical and theoretical -- Periodicals
Chemistry, Inorganic -- Periodicals
546.05 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/dt#!issueid=dt043040&type=current&issnprint=1477-9226 ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9dt01062a ↗
- Languages:
- English
- ISSNs:
- 1477-9226
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3517.830000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 10673.xml