Photochromic reaction in 3H-naphthopyrans studied by vibrational spectroscopy and quantum chemical calculations. Issue 22 (23rd May 2019)

• Record Type: Journal Article
• Authors: Brazevic, Sabina; Nizinski, Stanislaw; Szabla, Rafał; Rode, Michał F.; Burdzinski, Gotard
• Is Part Of: Physical chemistry chemical physics. Volume 21:Issue 22(2019)
• Page Start: 11861
• Page End: 11870
• Publication Date: 2019-05-23
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c9cp01451a
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Time resolved mid-IR spectroscopy facilitates selective detection of transoid- cis and transoid- trans species. Abstract : Structural details on the species involved in the photochromic reaction of 3 H -naphthopyrans in solution have been formerly determined using NMR spectroscopy. Herein we show that at room temperature time-resolved FT-IR spectroscopy is a simple and efficient tool for structural characterization of colored species generated upon continuous UV light irradiation of the model compound 3 H -naphthopyran: 3, 3-diphenyl-3 H -naphtho[2, 1- b ]pyran. In solution and in the polymer matrix phase, a colored species transoid- cis is formed after a single-photon excitation process, while transoid- trans is a secondary long-lived photoproduct generated after two-step excitation involving two photons. Understanding the reaction mechanism leading to long-lived colored species can help with the design of new 3 H -naphthopyran derivatives structurally optimized for making a photochromic reaction free from transoid- trans products, which is often important for applications. Ab initio calculations show that photoinduced ring-opening followed by isomerization occurs on a multidimensional potential-energy surface. The barriers separating the considered isomeric forms, both in the ground and in the excited state, help to interpret the step-by-step dynamics of the photoprocesses. The system is composed of a variety of ground state equilibrium forms. Each of them is characterized by fast excited-state deactivation pathways which may drive the system through different conical intersection regions.