Cp*CoIII‐Catalyzed Efficient Dehydrogenation of Secondary Alcohols. Issue 17 (26th July 2018)

• Record Type: Journal Article
• Authors: Gangwar, Manoj Kumar; Dahiya, Pardeep; Emayavaramban, Balakumar; Sundararaju, Basker
• Is Part Of: Chemistry, an Asian journal. Volume 13:Issue 17(2018)
• Page Start: 2445
• Page End: 2448
• Publication Date: 2018-07-26
• Subjects: alcohols -- catalysis -- cobalt -- ethers -- ketones; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201800697
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract: A novel, well‐defined molecular Cp*Co III complex was isolated and structurally characterized for the first time. The efficiency of this cobalt catalyst was demonstrated in the alcohol dehydrogenation and dehydrative coupling of secondary alcohols under mild conditions into ketones and ethers, respectively. Abstract : Acetone as an acceptor of H2 : A well‐defined, air‐stable Cp*Co(N, O)I complex was isolated for the first time and demonstrated its activity for an efficient dehydrogenation of alcohols into ketones and ethers under mild conditions.