The Curious Case of a Parasitic Twin of the Corroles. (22nd March 2018)
- Record Type:
- Journal Article
- Title:
- The Curious Case of a Parasitic Twin of the Corroles. (22nd March 2018)
- Main Title:
- The Curious Case of a Parasitic Twin of the Corroles
- Authors:
- Basumatary, Biju
Ramana Reddy, R. V.
Rahul,
Sankar, Jeyaraman - Abstract:
- Abstract: An expanded porphyrinoid has been obtained by a simple ring expansion from a contracted porphyrinoid, namely corrole. Spectroscopic, structural, and computational investigations reveal peculiar π‐conjugation and geometry. The effect of extended π‐conjugation is evident from perturbed redox behavior and photophysical properties. Owing to the strong diatropic ring current of the corrole and cross‐conjugation, the molecule exhibits a non‐aromatic nature for the expanded π‐circuit, as evident from NMR studies.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 18(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 18(2018)
- Issue Display:
- Volume 130, Issue 18 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 18
- Issue Sort Value:
- 2018-0130-0018-0000
- Page Start:
- 5146
- Page End:
- 5150
- Publication Date:
- 2018-03-22
- Subjects:
- Corrole -- Corrorin -- Erweiterte π-Systeme -- Hexaphyrin -- Porphyrinoide
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201801555 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 10639.xml