Achieving Ultralow Wear with Stable Nanocrystalline Metals. Issue 32 (25th June 2018)

• Record Type: Journal Article
• Authors: Curry, John F.; Babuska, Tomas F.; Furnish, Timothy A.; Lu, Ping; Adams, David P.; Kustas, Andrew B.; Nation, Brendan L.; Dugger, Michael T.; Chandross, Michael; Clark, Blythe G.; Boyce, Brad L.; Schuh, Christopher A.; Argibay, Nicolas
• Is Part Of: Advanced materials. Volume 30:Issue 32(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-06-25
• Subjects: friction -- metals -- nanocrystalline -- stable -- wear; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201802026
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: Recent work suggests that thermally stable nanocrystallinity in metals is achievable in several binary alloys by modifying grain boundary energies via solute segregation. The remarkable thermal stability of these alloys has been demonstrated in recent reports, with many alloys exhibiting negligible grain growth during prolonged exposure to near‐melting temperatures. Pt–Au, a proposed stable alloy consisting of two noble metals, is shown to exhibit extraordinary resistance to wear. Ultralow wear rates, less than a monolayer of material removed per sliding pass, are measured for Pt–Au thin films at a maximum Hertz contact stress of up to 1.1 GPa. This is the first instance of an all‐metallic material exhibiting a specific wear rate on the order of 10 −9 mm 3 N −1 m −1, comparable to diamond‐like carbon (DLC) and sapphire. Remarkably, the wear rate of sapphire and silicon nitride probes used in wear experiments are either higher or comparable to that of the Pt–Au alloy, despite the substantially higher hardness of the ceramic probe materials. High‐resolution microscopy shows negligible surface microstructural evolution in the wear tracks after 100k sliding passes. Mitigation of fatigue‐driven delamination enables a transition to wear by atomic attrition, a regime previously limited to highly wear‐resistant materials such as DLC. Abstract : A stable nanocrystalline alloy of Pt and Au is shown to be extremely resistant to mechanical abrasion and fatigue, having volumetric or specific wear rates comparable to diamond‐like carbon. This is the first report of a metal having such wear resistance.