Anomalous slip of ZrB2 ceramic grains during in-situ micropillar compression up to 500 °C. (April 2019)

• Record Type: Journal Article
• Authors: Csanádi, Tamás; Wehrs, Juri; Grasso, Salvatore; Reece, Mike; Michler, Johann; Dusza, Ján
• Is Part Of: International journal of refractory metals & hard materials. Volume 80(2019)
• Page Start: 270
• Page End: 276
• Publication Date: 2019-04
• Subjects: In-situ micro-compression -- Anisotropic deformation -- Slip activation -- Elevated temperature -- Zirconium diboride; Heat resistant alloys -- Periodicals; Refractory materials -- Periodicals; Metallography -- Periodicals; Alliages réfractaires -- Périodiques; Matériaux réfractaires -- Périodiques; Métallographie -- Périodiques; Heat resistant alloys; Metallography; Refractory materials; Periodicals; Electronic journals; 669.73
• DOI: 10.1016/j.ijrmhm.2019.01.021
• Languages: English
• ISSNs: 0263-4368

Abstract

Abstract: The anisotropic deformation behaviour of ZrB2 grains of basal and prismatic orientations in a polycrystalline ZrB2 sample was studied during in-situ micropillar compression at room temperature (RT), 350 °C and 500 °C. Micropillars were milled out of large grains by focused ion beam machining; the basal and prismatic orientations were previously identified using electron backscatter diffraction maps. The basal pillars showed brittle behaviour and cracking on the 10 1 ¯ 0 and 2 1 ¯ 1 ¯ 0 type prismatic planes that lead to their collapse. For this orientation, the yield/rupture stress ranged between 8 and 14 GPa and it exceeded 12 GPa even at 500 °C. In the prismatic orientation, considerable plasticity was observed, showing a temperature dependent yield stress from 6 to 8 GPa at room temperature to ~2GPa at 500 °C. The activated slip system family was identified as 10 1 ¯ 0 11 2 ¯ 3 type for all of the test temperatures (RT, 350 °C and 500 °C). Analysis of the Schmid-factors revealed that the plasticity of the prismatic micropillars is controlled by the temperature dependence of the critical resolved shear stress of the 10 1 ¯ 0 11 2 ¯ 3 slip systems. The brittleness of the basal micropillars was influenced by their defect structure (e.g. microcracks) and it was temperature independent due to the absence of slip activation. Highlights: Anisotropic deformation was observed in ZrB2 micropillars from room temperature to 500°C. Basal pillars showed cracking on the 10 1 ¯ 0 and 2 1 ¯ 1 ¯ 0 type prismatic planes with rupture stress ranged between 8 and 14 GPa. Prismatic pillars exhibited considerable plasticity and temperature dependent yield stress from 6-8 GPa to ~2 GPa. The activation of the 10 1 ¯ 0 11 2 ¯ 3 type slip system was identified for all of the test temperatures (RT, 350°C and 500°C).