Ferrocene-containing acylhydrazone receptors: synthesis, structures and electrochemical anion recognition characteristics. (1st August 2017)

• Record Type: Journal Article
• Authors: Li, Xia; Liu, Wei; Song, Maoping
• Is Part Of: Journal of chemical research. Volume 41:Number 8(2017)
• Page Start: 491
• Page End: 496
• Publication Date: 2017-08-01
• Subjects: Chemistry -- Research -- Periodicals; Chemistry -- Periodicals; 540.5
• DOI: 10.3184/174751917X15017625991813
• Languages: English
• ISSNs: 1747-5198

Abstract

Ferrocene-containing redox receptors bearing the 2-(quinolin-8-yloxy)acetohydrazide (qa) moiety on one arm, [Fe(Cpqa)Cp], or two arms, [Fe(Cpqa)2], have been synthesised and the X-ray crystal structure of [Fe(Cpqa)2] determined. [Fe(Cpqa)2] can sense H2PO4– both electrochemically and selectively even in the presence of a large excess of Cl– and ClO4–.