1, 10-Phenanthroline-Catalysed Cr(VI) Oxidation of D-Sorbitol and D-Mannitol in Aqueous Micellar Media. (3rd June 2009)
- Record Type:
- Journal Article
- Title:
- 1, 10-Phenanthroline-Catalysed Cr(VI) Oxidation of D-Sorbitol and D-Mannitol in Aqueous Micellar Media. (3rd June 2009)
- Main Title:
- 1, 10-Phenanthroline-Catalysed Cr(VI) Oxidation of D-Sorbitol and D-Mannitol in Aqueous Micellar Media
- Authors:
- Bayen, Ruhidas
Das, Asim - Abstract:
- Chromic acid oxidation of two polyols (D-sorbitol and D-mannitol) to their corresponding aldohexoses in the presence of phenanthroline (phen) involves as the active oxidant, a Cr(VI)-phen complex formed in a rapid pre-equilibrium step. The observed micellar effect (rate acceleration by an anionic surfactant and rate retardation by a cationic surfactant) conforms with the proposed reaction mechanism.
- Is Part Of:
- Progress in reaction kinetics and mechanism. Volume 34:Number 2(2009)
- Journal:
- Progress in reaction kinetics and mechanism
- Issue:
- Volume 34:Number 2(2009)
- Issue Display:
- Volume 34, Issue 2 (2009)
- Year:
- 2009
- Volume:
- 34
- Issue:
- 2
- Issue Sort Value:
- 2009-0034-0002-0000
- Page Start:
- 165
- Page End:
- 181
- Publication Date:
- 2009-06-03
- Subjects:
- Chemical kinetics -- Periodicals
541.39405 - Journal URLs:
- http://stl.publisher.ingentaconnect.com/content/stl/prk ↗
https://journals.sagepub.com/home/prk ↗
http://www.sciencereviews2000.co.uk/ ↗ - DOI:
- 10.3184/146867809X452622 ↗
- Languages:
- English
- ISSNs:
- 1468-6783
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 10491.xml