The Study of a New Method to Determine Copper Ion by Square-Wave Voltammetry-Extraction Iodometry at the Liquid/Liquid Interfaces. (14th December 2008)

• Record Type: Journal Article
• Authors: Shi, Changyan; Xie, Shaoai; Jia, Jinping
• Other Names: Stockwell Peter Academic Editor.
• Is Part Of: Journal of automated methods & management in chemistry. Volume 2008(2008)
• Publication Date: 2008-12-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1155/2008/453429
• Languages: English
• ISSNs: 1463-9246

Abstract

Abstract : A new method of indirect determination ofCu 2 + was developed based on square-wave voltammetry by the oxidation of iodide in organic solvent at the liquid/liquid (L/L) interface. The limit of detection for the determination ofCu 2 + in this method was found to be5 × 10 −4 mol/L, and the concentration ranged up to1 × 10 −2 mol/L gave a linear limiting current versus concentration response. For the same simulated wastewater, this method showed high accuracy compared with the result tested by sodium diethyldithiocarbamate extraction spectrophotometry. This approach could be applied to the indirect determination of the oxidative heavy metals in the industrial wastewater.