Perfluorinated tert‐Butoxides of Tin(II): The Dimeric Alkoxide and Its Monomeric Ate Complex. Issue 3 (29th October 2018)

• Record Type: Journal Article
• Authors: Schleep, Mario; Hettich, Clarissa; Glatz, Jana Maren; Kratzert, Daniel; Beichel, Witali; Velázquez Rojas, Jennifer; Scherer, Harald; Krossing, Ingo
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 645:Issue 3(2019)
• Page Start: 301
• Page End: 308
• Publication Date: 2018-10-29
• Subjects: Main group chemistry -- Tin -- Density functional calculations -- Lewis acids -- Fluorinated materials; Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201800388
• Languages: English
• ISSNs: 0044-2313

Abstract

Abstract : Surprisingly little is known about fluorinated tin(II) alkoxides. Here the synthesis and characterization of Sn(O R F )2 [O R F = OC(CF3 )3 ] and the crystal structures of its adducts with phenanthroline and dppe are reported. In addition, its ate complex [Sn(O R F )3 ] – was synthesized with lithium or sodium as cation and as acetonitrile adduct. The thermolytic behavior of both, the alkoxide and the lithium stannate(II), was investigated together with first electrochemical measurements of Li[Sn(O R F )3 ]. Abstract :