Investigation of the self-discharge behaviors of the LiMn2O4 cathode at elevated temperatures: in situ X-ray diffraction analysis and a co-doping mitigation strategy. Issue 21 (20th May 2019)

• Record Type: Journal Article
• Authors: Tang, Xiaoyu; Zhou, Jie; Bai, Miao; Wu, Weiwei; Li, Shaowen; Ma, Yue
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 21(2019)
• Page Start: 13364
• Page End: 13371
• Publication Date: 2019-05-20
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c9ta02718a
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : The lithium ion re-intercalated into the LiMn2 O4 lattice during self-discharge. Abstract : The practical application of lithium-ion batteries at elevated temperatures is significantly hampered by their poor cyclabilities and self-discharge behaviors. In this study, we investigated real-time structural evolution of the lithium manganese oxide cathode (LiMn2 O4, LMO) in the idle charged state as well as the origin of the self-discharge process via in situ X-ray diffraction analysis. Moreover, we proposed a facile and scalable co-doping strategy for the incorporation of Al 3+, F − and PO4 3− into the LMO spinel structure; in addition, the thermal stability of the LMO samples was ameliorated by suppressing the parasitic formation of a Li-rich phase of LMO upon long-term cycling. When evaluated at room temperature, the modified LMO exhibits the impressive areal mass loading of up to 17.8 mg cm −2, the highest areal capacities of ∼1.4 mA h cm −2 at 5C, robust cyclability even after 1000 charge/discharge cycles, lower polarization voltage and significant mitigation of the self-discharge process at the elevated temperature of 55 °C; thus, this low-cost scalable modification strategy makes the LMO cathode commercially feasible for high-temperature applications.