Silane catecholates: versatile tools for self-assembled dynamic covalent bond chemistry. Issue 43 (8th May 2019)

• Record Type: Journal Article
• Authors: Kawakami, Yoshiteru; Ogishima, Tsuyoshi; Kawara, Tomoki; Yamauchi, Shota; Okamoto, Kazuhiko; Nikaido, Singo; Souma, Daiki; Jin, Ren-Hua; Kabe, Yoshio
• Is Part Of: Chemical communications. Volume 55:Issue 43(2019)
• Page Start: 6066
• Page End: 6069
• Publication Date: 2019-05-08
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c9cc02103e
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Shape-persistent macrocycles and 3D nanocages have been prepared in one-pot under MeCN-promoted dynamic covalent bond conditions starting from silane catecholates, whose structures were confirmed by X-ray crystallography. Abstract : Shape-persistent macrocycles and 3D nanocages have been prepared in one-pot under MeCN-promoted dynamic covalent bond conditions starting from silane catecholates, whose structures were confirmed by X-ray crystallography. Cation-exchange reactions of macrocycles and nanocages were performed along with the encapsulation of ammonium ions within the cavity of an anionic macrocycle and a tetrahedral nanocage.