Amidinium–carboxylate salt bridge mediated proton-coupled electron transfer in a donor–acceptor supramolecular system12. Issue 5 (29th January 2019)

• Record Type: Journal Article
• Authors: Ren, Xiaolei; Wang, Xiaohua; Sun, Yuren; Chi, Xiaodong; Mangel, Daniel; Wang, Hongyu; Sessler, Jonathan L.
• Is Part Of: Organic chemistry frontiers. Volume 6:Issue 5(2019)
• Page Start: 584
• Page End: 590
• Publication Date: 2019-01-29
• Subjects: Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1039/c8qo01408f
• Languages: English
• ISSNs: 2052-4110

Abstract

Abstract : A supramolecular polymer that allows for intrapolymer proton-coupled photoinduced electron transfer was constructed by means of amidinium-carboxylate salt bridges. Abstract : A supramolecular polymer, 3T-DPP, that undergoes photoinduced proton-coupled electron transfer was constructed by means of amidinium-carboxylate salt bridges that serve to link terthiophene electron donors and diketopyrrolopyrrole electron acceptors with a 1 : 1 binding constant of 1.13 × 10 5 M −1 in N -methyl pyrrolidone.