Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes. (12th April 2019)
- Record Type:
- Journal Article
- Title:
- Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes. (12th April 2019)
- Main Title:
- Magnesium‐Catalyzed Hydroboration of Terminal and Internal Alkynes
- Authors:
- Magre, Marc
Maity, Bholanath
Falconnet, Alban
Cavallo, Luigi
Rueping, Magnus - Abstract:
- Abstract: A magnesium‐catalyzed hydroboration of alkynes providing good yields and selectivities for a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been developed. The compatibility with many functional groups makes this magnesium catalyzed procedure attractive for late stage functionalization. Experimental mechanistic investigations and DFT calculations reveal insights into the reaction mechanism of the magnesium catalyzed protocol.
- Is Part Of:
- Angewandte Chemie. Volume 131:Number 21(2019)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 131:Number 21(2019)
- Issue Display:
- Volume 131, Issue 21 (2019)
- Year:
- 2019
- Volume:
- 131
- Issue:
- 21
- Issue Sort Value:
- 2019-0131-0021-0000
- Page Start:
- 7099
- Page End:
- 7103
- Publication Date:
- 2019-04-12
- Subjects:
- Alkine -- Dichtefunktionalrechnungen -- Hydroborierungen -- Magnesium -- Vinylboran
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201902188 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 10415.xml