Photocatalytic carbanion generation – benzylation of aliphatic aldehydes to secondary alcohols. Issue 19 (25th April 2019)
- Record Type:
- Journal Article
- Title:
- Photocatalytic carbanion generation – benzylation of aliphatic aldehydes to secondary alcohols. Issue 19 (25th April 2019)
- Main Title:
- Photocatalytic carbanion generation – benzylation of aliphatic aldehydes to secondary alcohols
- Authors:
- Donabauer, Karsten
Maity, Mitasree
Berger, Anna Lucia
Huff, Gregory S.
Crespi, Stefano
König, Burkhard - Abstract:
- Abstract : We present a redox-neutral method for the photocatalytic generation of carbanions. Abstract : We present a redox-neutral method for the photocatalytic generation of carbanions. Benzylic carboxylates are photooxidized by single electron transfer; immediate CO2 extrusion and reduction of the in situ formed radical yields a carbanion capable of reacting with aliphatic aldehydes as electrophiles giving the Grignard analogous reaction product.
- Is Part Of:
- Chemical science. Volume 10:Issue 19(2019)
- Journal:
- Chemical science
- Issue:
- Volume 10:Issue 19(2019)
- Issue Display:
- Volume 10, Issue 19 (2019)
- Year:
- 2019
- Volume:
- 10
- Issue:
- 19
- Issue Sort Value:
- 2019-0010-0019-0000
- Page Start:
- 5162
- Page End:
- 5166
- Publication Date:
- 2019-04-25
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/SC ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9sc01356c ↗
- Languages:
- English
- ISSNs:
- 2041-6520
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3151.490000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 10403.xml