Synthesis of isoquinolone via rhodium(III)-catalyzed C-H activation with 1, 4, 2-dioxazol-5-ones as oxidizing directing group. Issue 23 (7th June 2019)

• Record Type: Journal Article
• Authors: Zhu, Huajian; Zhuang, Rangxiao; Zheng, Wenya; Fu, Liping; Zhao, Yuanke; Tu, Luping; Chai, Yitao; Zeng, Linghui; Zhang, Chong; Zhang, Jiankang
• Is Part Of: Tetrahedron. Volume 75:Issue 23(2019)
• Page Start: 3108
• Page End: 3112
• Publication Date: 2019-06-07
• Subjects: 1, 4, 2-Dioxazol-5-ones -- Rhodium(III)-catalyzed -- C-H activation -- Oxidizing directing groups -- Isoquinolones; Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1016/j.tet.2019.04.054
• Languages: English
• ISSNs: 0040-4020

Abstract

Abstract: An efficient rhodium-catalyzed direct C-H activation for the synthesis of isoquinolone with 1, 4, 2-dioxazol-5-ones as oxidizing directing groups have been developed, which featured mild reaction conditions, short reaction time and satisfactory yield. Graphical abstract: An efficient approach to isoquinolone have been developed, which featured in completing expeditiously under mild conditions with satisfactory yield.Image 1