A Novel Thermomorphic System for Electrocatalytic Diels‐Alder Reactions1. Issue 6 (15th April 2019)
- Record Type:
- Journal Article
- Title:
- A Novel Thermomorphic System for Electrocatalytic Diels‐Alder Reactions1. Issue 6 (15th April 2019)
- Main Title:
- A Novel Thermomorphic System for Electrocatalytic Diels‐Alder Reactions1
- Authors:
- Imada, Yasushi
Shida, Naoki
Okada, Yohei
Chiba, Kazuhiro - Abstract:
- Summary of main observation and conclusion: The discovery that lithium bis(trifluoromethane)sulfonamide (LiTFSI)/1‐nitropropane (PrNO2 ) solution functions as a less polar alternative to lithium perchlorate (LiClO4 )/nitromethane (MeNO2 ) solution has led to the development of a novel thermomorphic system for electrocatalytic Diels‐Alder reactions. Methyl cyclohexane (Me‐ c ‐Hex) can form a monophasic condition with LiTFSI/PrNO2 solution at room temperature, enabling the use of hydrophobic dienophiles. After the electrochemical reaction, a biphasic condition can be formed at –50°C, where the cycloadducts are selectively recovered from the upper Me‐ c ‐Hex phase and the remaining lower LiTFSI/PrNO2 solution can be reused. Abstract : Methyl cyclohexane can form a thermomorphic system with lithium bis(trifluoromethane)sulfonamide/1‐nitropropane solution, where biphasic and monophasic conditions were reversibly switched over a practical temperature range. The monophasic condition serves as a less polar electrolyte solution, enabling the use of hydrophobic dienophiles for electrocatalytic Diels‐Alder reactions.
- Is Part Of:
- Chinese journal of chemistry. Volume 37:Issue 6(2019)
- Journal:
- Chinese journal of chemistry
- Issue:
- Volume 37:Issue 6(2019)
- Issue Display:
- Volume 37, Issue 6 (2019)
- Year:
- 2019
- Volume:
- 37
- Issue:
- 6
- Issue Sort Value:
- 2019-0037-0006-0000
- Page Start:
- 557
- Page End:
- 560
- Publication Date:
- 2019-04-15
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1614-7065 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/cjoc.201900053 ↗
- Languages:
- English
- ISSNs:
- 1001-604X
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3180.299500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 10333.xml