Surfactant-Free Microwave-Assisted Synthesis of Fe-Doped ZnO Nanostars as Photocatalyst for Degradation of Tropaeolin O in Water under Visible Light. (9th July 2015)

• Record Type: Journal Article
• Authors: Kwong, Tsz-Lung; Yung, Ka-Fu
• Other Names: Willander Magnus Academic Editor.
• Is Part Of: Journal of nanomaterials. Volume 2015(2015)
• Publication Date: 2015-07-09
• Subjects: Nanostructured materials -- Periodicals; Nanotechnology -- Periodicals; Nanomatériaux; Nanostructured materials; Nanotechnology; Nanostructures; Nanotechnology; Periodicals; Fulltext; Internet Resources; Periodicals; 620.115
• DOI: 10.1155/2015/190747
• Languages: English
• ISSNs: 1687-4110

Abstract

Abstract : Iron-doped zinc oxide nanostar was synthesized by the microwave-assisted surfactant-free hydrolysis method. The as-synthesized Fe-doped ZnO nanostars catalyst was fully characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), powder X-ray diffraction (XRD), and diffuse reflectance UV-vis spectroscopy (UV-DRA). The photocatalytic activity of the photocatalyst was investigated for the photocatalytic degradation of Tropaeolin O under visible light irradiation. It is observed that the doping of Fe ions enhances the absorption of the visible light and thus the photocatalytic degradation rate of Tropaeolin O would increase. Despite the Taguchi orthogonal experimental design method, the photocatalytic conversion could be achieved at 99.8% in the Fe-doped ZnO catalyzed photodegradation reaction under the optimal reaction conditions of catalyst loading (30 mg), temperature (60°C), light distance (0 cm), initial pH (pH = 9), and irradiation time (3 h). The Fe-doped ZnO photocatalyst can also be easily recovered and directly reused for eight cycles with over 70% conversion.