Bulk synthesis of graphene nanosheets from plastic waste: An invincible method of solid waste management for better tomorrow. (1st April 2019)

• Record Type: Journal Article
• Authors: Pandey, Sandeep; Karakoti, Manoj; Dhali, Sunil; Karki, Neha; SanthiBhushan, Boddepalli; Tewari, Chetna; Rana, Sravendra; Srivastava, Anurag; Melkani, Anand B.; Sahoo, Nanda Gopal
• Is Part Of: Waste management. Volume 88(2019)
• Page Start: 48
• Page End: 55
• Publication Date: 2019-04-01
• Subjects: DFT -- Graphene -- Plastic waste -- Nanoclay -- Raman spectroscopy; Hazardous wastes -- Periodicals; Refuse and refuse disposal -- Periodicals; 363.728
• DOI: 10.1016/j.wasman.2019.03.023
• Languages: English
• ISSNs: 0956-053X

Abstract

Graphical abstract: Highlights: This work deals with the conversion of plastic waste into graphene nanosheets. This is the cheapest technology for the mass production of graphene nanosheets. The results of this method reveals the utility and thus ensures the product quality. The present work is dedicated to rapid and advance solution for plastic pollution. This method left the significant impression to manage the both ecology and economy. Abstract: Waste plastic management and converting it into value added products is one of the greatest challenges before the scientific community. The present work reports a cost effective, environment friendly and mass production capable method for upcycling of solid plastic waste into value added product (graphene). A two step pyrolysis processes i.e. firstly at 400 °C in presence of nanoclay followed by at 750 °C under nitrogen atmosphere was performed to obtain a black charged residue. Raman spectroscopy was performed on the obtained residue, where the observed D and G bands at 1342 cm −1 and 1594 cm −1, respectively, confirm the synthesis of graphene nano sheets. In addition, a broad 2D band at 2790 cm −1 confirm the presence of few layer graphene nano sheets. The obtained graphene nanosheets were also confirmed through the computational data by Gaussian09, where the peaks at 1379 cm −1 and 1596 cm −1 for D and G band, respectively, make a good agreement with experimental data. TEM, FT-IR and EDX spectroscopy were also performed to confirm the synthesis of graphene nanosheets including the functional group identification and quantitative analysis for elements, respectively.