Identification of Phase Control of Carbon‐Confined Nb2O5 Nanoparticles toward High‐Performance Lithium Storage. Issue 18 (18th March 2019)

• Record Type: Journal Article
• Authors: Meng, Jiashen; He, Qiu; Xu, Linhan; Zhang, Xingcai; Liu, Fang; Wang, Xuanpeng; Li, Qi; Xu, Xiaoming; Zhang, Guobin; Niu, Chaojiang; Xiao, Zhitong; Liu, Ziang; Zhu, Zizhong; Zhao, Yan; Mai, Liqiang
• Is Part Of: Advanced energy materials. Volume 9:Issue 18(2019)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-03-18
• Subjects: carbon‐confined Nb2O5 -- in situ XRD -- lithium storage -- phase control -- theoretical calculation; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201802695
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: Niobium pentoxides (Nb2 O5 ) have attracted extensive interest for ultrafast lithium‐ion batteries due to their impressive rate/capacity performance and high safety as intercalation anodes. However, the intrinsic insulating properties and unrevealed mechanisms of complex phases limit their further applications. Here, a facile and efficient method is developed to construct three typical carbon‐confined Nb2 O5 (TT‐Nb2 O5 @C, T‐Nb2 O5 @C, and H‐Nb2 O5 @C) nanoparticles via a mismatched coordination reaction during the solvothermal process and subsequent controlled heat treatment, and different phase effects are investigated on their lithium storage properties on the basis of both experimental and computational approaches. The thin carbon coating and nanoscale size can endow Nb2 O5 with a high surface area, high conductivity, and short diffusion length. As a proof‐of‐concept application, when employed as LIB anode materials, the resulting T‐Nb2 O5 @C nanoparticles display higher rate capability and better cycling stability as compared with TT‐Nb2 O5 @C and H‐Nb2 O5 @C nanoparticles. Furthermore, a synergistic effect is investigated and demonstrated between fast diffusion pathways and stable hosts in T‐Nb2 O5 for ultrafast and stable lithium storage, based on crystal structure analysis, in situ X‐ray diffraction analysis, and density functional theoretical calculations. Therefore, the proposed synthetic strategy and obtained deep insights will stimulate the development of Nb2 O5 for ultrafast and long‐life LIBs. Abstract : A facile and efficient method is developed to construct three typical carbon‐confined Nb2 O5 (TT‐Nb2 O5 @C, T‐Nb2 O5 @C, and H‐Nb2 O5 @C) nanoparticles via a mismatched coordination reaction during the solvothermal process and subsequent heat treatment. Further, different phase effects on their lithium storage properties are systematically investigated based on both experimental and computational approaches.