Sulfonate based ionic liquid incorporated polymer electrolytes for Magnesium secondary battery. Issue 9 (13th June 2019)

• Record Type: Journal Article
• Authors: Ponmani, S.; Ramesh Prabhu, M.
• Is Part Of: Polymer-plastics technology and materials. Volume 58:Issue 9(2019)
• Page Start: 978
• Page End: 991
• Publication Date: 2019-06-13
• Subjects: EMITF -- ionic conductivity -- cyclic Voltammetry -- dielectric modulus -- LSV; Polymers -- Periodicals; Polymerization -- Periodicals; Plastics -- Periodicals; Plastics; Polymerization; Polymers; Periodicals; 668
• DOI: 10.1080/03602559.2018.1520259
• Languages: English
• ISSNs: 2574-0881

Abstract

ABSTRACT: The polymer electrolytes comprising of PVdF-HFP/PVAc/Mg(ClO4 )2 as salt based polymer blend electrolytes derived from the addition of varying amounts of 1-ethyl – 3-methylimidazolium trifluoromethane sulfonate [EMITF], as dopant were synthesized in the form of films by solution-casting method. The XRD and FTIR patterns confirm the formation of an amorphous phase and also that complex formation between the polymers, salt and ionic liquid. The SEM images show that the polymer electrolyte exhibit a enormous pores, remarkably, the maximum ionic conductivity is obtained in the case of the typical polymer system I3 is found to be 9.122 × 10 −4 Scm −1 at 303 K.