A correlative four-dimensional study of phase-separation at the subnanoscale to nanoscale of a NiAl alloy. (1st June 2019)

• Record Type: Journal Article
• Authors: Plotnikov, Elizaveta Y.; Mao, Zugang; Baik, Sung-Il; Yildirim, Mehmet; Li, Yongsheng; Cecchetti, Daniel; Noebe, Ronald D.; Martin, Georges; Seidman, David N.
• Is Part Of: Acta materialia. Volume 171(2019)
• Page Start: 306
• Page End: 333
• Publication Date: 2019-06-01
• Subjects: Nickel-based superalloys -- Atom-probe tomography -- Temporal evolution -- Monovacancy-mediated lattice kinetic Monte Carlo -- Lifshit-Slyozov (LS) model; Materials -- Periodicals; Materials science -- Periodicals; Materials -- Mechanical properties -- Periodicals; Metallurgy -- Periodicals; Chemistry, Inorganic -- Periodicals; 620.112
• DOI: 10.1016/j.actamat.2019.03.016
• Languages: English
• ISSNs: 1359-6454

Abstract

Abstract: The temporal evolution of ordered γ′(L12 )-precipitates precipitating in a disordered γ(f.c.c.) matrix is studied in extensive detail for a Ni-12.5 Al at.% alloy aged at 823 K (550 °C), for times ranging from 0.08 to 4096 h. Three-dimensional atom-probe tomography (3-D APT) results are compared to monovacancy-mediated lattice-kinetic Monte Carlo (LKMC1 ) simulations on a rigid lattice, which include monovacancy-solute binding energies through 4th nearest-neighbor distances, for the same mean composition and aging temperature. The temporal evolution of the measured values of the mean radius, 〈 R ( t ) 〉, number density, aluminum supersaturations, and volume fraction of the γ′(L12 )-precipitates are compared to the predictions of a modified version of the Lifshitz-Slyozov diffusion-limited coarsening model due to Calderon, Voorhees et al. The resulting experimental rate constants are used to calculate the Gibbs interfacial free-energy between the γ(f.c.c.)- and γ′(L12 )-phases, which enter the model, using data from two thermodynamic databases, and its value is compared to all exiting values. The diffusion coefficient for coarsening is calculated utilizing the same rate-constants and compared to all archival diffusivities, not determined from coarsening experiments, and it is demonstrated to be the inter-diffusivity, D ˜, of Ni and Al. The monovacancy-mediated LKMC1 simulation results are in good agreement with our 3-D APT data. The compositional interfacial width, for the {100}-interface, between the γ(f.c.c.)- and γ'(L12 )-phases, decreases continuously with increasing aging time and 〈 R ( t ) 〉, both for the 3-D APT results and the monovacancy-mediated LKMC1 simulations, in disagreement with an ansatz intrinsic to the trans-interface diffusion-controlled coarsening model, which assumes the exact opposite trend for binary alloys. Graphical abstract: Image 1