Design and reactivity of pentapyridyl metal complexes for ammonia oxidation. Issue 35 (12th April 2019)
- Record Type:
- Journal Article
- Title:
- Design and reactivity of pentapyridyl metal complexes for ammonia oxidation. Issue 35 (12th April 2019)
- Main Title:
- Design and reactivity of pentapyridyl metal complexes for ammonia oxidation
- Authors:
- Johnson, Samantha I.
Heins, Spencer P.
Klug, Christina M.
Wiedner, Eric S.
Bullock, R. Morris
Raugei, Simone - Abstract:
- Abstract : Computational and experimental work shows that Mo pentapyridal complexes can oxidize ammonia in the presence of a chemical mediator and evolve N2 . Abstract : Oxidation of NH3 to N2 by pentapyridyl metal complexes via hydrogen atom abstraction was investigated computationally. Quantum chemical analysis reveals insights on orbital symmetry requirements for efficient NH3 oxidation. The most promising complex, [(PY5)Mo(NH3 )] 2+, was studied experimentally. It shows conversion of NH3 to N2 upon treatment with 2, 4, 6-tri- tert -butylphenoxyl radical.
- Is Part Of:
- Chemical communications. Volume 55:Issue 35(2019)
- Journal:
- Chemical communications
- Issue:
- Volume 55:Issue 35(2019)
- Issue Display:
- Volume 55, Issue 35 (2019)
- Year:
- 2019
- Volume:
- 55
- Issue:
- 35
- Issue Sort Value:
- 2019-0055-0035-0000
- Page Start:
- 5083
- Page End:
- 5086
- Publication Date:
- 2019-04-12
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc01249d ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 10137.xml