Cooperative reduction of various RAFT polymer terminals using hydrosilane and thiol via polarity reversal catalysis. Issue 37 (2nd April 2019)
- Record Type:
- Journal Article
- Title:
- Cooperative reduction of various RAFT polymer terminals using hydrosilane and thiol via polarity reversal catalysis. Issue 37 (2nd April 2019)
- Main Title:
- Cooperative reduction of various RAFT polymer terminals using hydrosilane and thiol via polarity reversal catalysis
- Authors:
- Uchiyama, Mineto
Satoh, Kotaro
Kamigaito, Masami - Abstract:
- Abstract : Cooperative reduction of various thiocarbonylthio polymer terminals was investigated using thiol as a polarity reversal catalyst with hydrosilane as a reducing agent. Abstract : Cooperative reduction of thiocarbonylthio terminals of polymers obtained by RAFT polymerization was investigated using a catalytic amount of thiol as a polarity reversal catalyst in conjunction with hydrosilane as a reducing agent. A combination of C12 H25 SH and Ph3 SiH enabled the complete removal of xanthate, dithiobenzoate, and trithiocarbonate groups from poly(vinyl acetate), polystyrene, and poly(methyl acrylate) under the radical conditions.
- Is Part Of:
- Chemical communications. Volume 55:Issue 37(2019)
- Journal:
- Chemical communications
- Issue:
- Volume 55:Issue 37(2019)
- Issue Display:
- Volume 55, Issue 37 (2019)
- Year:
- 2019
- Volume:
- 55
- Issue:
- 37
- Issue Sort Value:
- 2019-0055-0037-0000
- Page Start:
- 5327
- Page End:
- 5330
- Publication Date:
- 2019-04-02
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c9cc00900k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 10093.xml