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Visible-light-mediated guest trapping in a photosensitizing porous coordination network: metal-free C–C bond-forming modification of metal–organic frameworks for aqueous-phase herbicide adsorption. Issue 37 (17th April 2019)
Record Type:
Journal Article
Title:
Visible-light-mediated guest trapping in a photosensitizing porous coordination network: metal-free C–C bond-forming modification of metal–organic frameworks for aqueous-phase herbicide adsorption. Issue 37 (17th April 2019)
Main Title:
Visible-light-mediated guest trapping in a photosensitizing porous coordination network: metal-free C–C bond-forming modification of metal–organic frameworks for aqueous-phase herbicide adsorption
Abstract : Metal-free visible-light-mediated C–C bond-forming modification of metal–organic frameworks (MOFs) for aqueous-phase herbicide adsorption. Abstract : A series of furan/thiophene-derived Cr-MIL-101s were obtained via visible-light-mediated C–C bond-forming catalysis within photosensitizing porous materials. The guest trapping process was achieved under very mild and metal-free conditions, affording newly functionalized MOFs with more π–π stacking, hydrogen bonding properties and excellent adsorption capacity in removing herbicides from aquatic environments.