Synthesis, structure, and property of a cd(II) 3D coordinated polymer with 2-fold parallel interpenetrated network based on 5-(4-hydroxypyridinium-1-yl) isophthalic acid ligand. Issue 8 (3rd August 2018)

• Record Type: Journal Article
• Authors: Li, Fu-An; Wang, Li; Yang, Wei-Chun; Li, Qing-Bin
• Is Part Of: Inorganic and nano-metal chemistry. Volume 48:Issue 8(2018)
• Page Start: 399
• Page End: 403
• Publication Date: 2018-08-03
• Subjects: 5-(4-hydroxypyridinium-1-ylmethyl)isophthalic acid -- 1, 1′-(1, 4-butanediyl)bis(imidazole) -- cadmium -- interpenetrated network; Inorganic compounds -- Synthesis -- Periodicals; Nanostructured materials -- Periodicals; Reactivity (Chemistry) -- Periodicals; Inorganic compounds -- Synthesis; Nanostructured materials; Reactivity (Chemistry); Periodicals; 546
• DOI: 10.1080/24701556.2019.1569680
• Languages: English
• ISSNs: 2470-1556

Abstract

Abstract: A Cd(II) coordination polymer, {[Cd(L)(1, 4-bbi)0.5 (H2 O)]·H2 O} n (1 ), where H2 L = 5-(4-hydroxypyridinium-1-ylmethyl)isophthalic acid, 1, 4-bbi = 1, 1′-(1, 4-butanediyl)bis(imidazole), has been hydrothermally synthesized and structurally characterized by X-ray diffraction analyses and further characterized by infrared spectra (IR), elemental analyses, PXRD, and thermogravimetric (TG) analyses. Compound1 reveals a 2-fold interpenetrating 3D framework with (4·8 2 ·10 3 ) (4·8 2 ) topology, and the Cd center has a distorted octahedral environment. Meanwhile, the luminescent property of the title compound (1 ) has also been investigated in detail.