MnFeTiOx/attapulgite catalysts with excellent potassium resistance for SCR of NOx with NH3 at low temperatures. Issue 7 (26th February 2019)

• Record Type: Journal Article
• Authors: Tang, Yiran; Tao, Yiyang; Wu, Jiayi; Xu, Linjing; Huang, Xiaoyan; Zhou, Xingmeng; Xie, Aijuan; Luo, Shiping; Yao, Chao; Li, Xiazhang
• Is Part Of: Journal of materials research. Volume 34:Issue 7(2019)
• Page Start: 1188
• Page End: 1199
• Publication Date: 2019-02-26
• Subjects: MnFeTiOx/ATP, -- low temperature, -- selective catalytic reduction, -- NOx conversion, -- potassium resistance; Materials -- Research -- Periodicals; 620.1105
• DOI: 10.1557/jmr.2019.31
• Languages: English
• ISSNs: 0884-2914

Abstract

Abstract: Abstract : A series of metal oxides (MnFeO x, MnCrO x, MnTiO x, and MnFeTiO x ) supported on attapulgite (ATP) were synthesized by coprecipitation for the low-temperature selective catalytic reduction (SCR) of NO x with NH3 . Then, they were subjected to appropriate characterizations for their properties (XRD, TEM, BET, XPS, etc.). The catalytic activity of MnFeTiO x /ATP catalyst was over 95% NO x conversion within a wide temperature window between of 175 and 300 °C, and 88% N2 selectivity. Moreover, MnFeTiO x /ATP presented excellent potassium resistance relative to the traditional V–W–Ti catalyst, and its denitration performance was significantly improved. The NO x conversion rate could be restored to nearly 90% at 210 °C after removing potassium via washing of K–MnFeTiO x /ATP. In addition, the MnFeTiO x /ATP showed better SO2 resistance and stability than the traditional V–W–Ti catalyst. Therefore, the MnFeTiO x /ATP catalyst has been proved to have broad prospects in NH3 -SCR.