An Efficient Method for Chemoselective Reduction of Nitro Compounds Using Bimetallic Fe‐Ni NPs/H3PW12O40.×H2O System. Issue 10 (7th July 2014)

• Record Type: Journal Article
• Authors: Rezazadeh, Soodabeh; Akhlaghinia, Batool; Goharshadi, Elaheh K.; Sarvari, Hossein
• Is Part Of: Journal of the Chinese Chemical Society. Volume 61:Issue 10(2014:Oct.)
• Page Start: 1108
• Page End: 1114
• Publication Date: 2014-07-07
• Subjects: Amines -- Bimetallic Fe‐Ni NPs -- Chemoselective reduction; Chemistry -- Periodicals; Electronic journals; 540.5
• DOI: 10.1002/jccs.201400134
• Languages: English
• ISSNs: 0009-4536

Abstract

Abstract: The selective reduction of nitro compounds by treatment with bimetallic Fe‐Ni nanoparticles (NPs) and tungestophosphoric acid hydrate (H3 PW12 O40 .×H2 O) in H2 O is reported. The method has been applied to a broad range of nitro compounds with different sensitive functionalities, including halides, carbonyl, hydroxyl, aldehyde, methyl, acetyl, nitrile, and ester substituents with excellent yields. The reaction yielded single product in all cases with very high yield. The simple experimental procedure and easy purification make the protocol advantageous. Abstract : The selective reduction of nitro compounds by treatment with bimetallic Fe‐Ni nanoparticles (NPs) and tungestophosphoric acid hydrate (H3 PW12 O40 .×H2 O) in H2 O is reported. The method has been applied to a broad range of nitro compounds with different sensitive functionalities, including halides, carbonyl, hydroxyl, aldehyde, methyl, acetyl, nitrile, and ester substituents with excellent yields.