Dinuclear HgII tetracarbene complex-triggered aggregation-induced emission for rapid and selective sensing of Hg2+ and organomercury species12. Issue 15 (14th March 2019)

• Record Type: Journal Article
• Authors: Yuan, Bin; Wang, Dong-Xia; Zhu, Li-Na; Lan, Yan-Long; Cheng, Meng; Zhang, Li-Ming; Chu, Jun-Qing; Li, Xiao-Zeng; Kong, De-Ming
• Is Part Of: Chemical science. Volume 10:Issue 15(2019)
• Page Start: 4220
• Page End: 4226
• Publication Date: 2019-03-14
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c8sc05714a
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : Mercury-mediated chelate ring formation and subsequent aggregation gives strong fluorescence for rapid and selective sensing of Hg 2+ and organomercury. Abstract : Rapid, reliable and highly selective detection of mercury species, including Hg 2+ ions and organomercury, is of significant importance for environmental protection and human health. Herein, a new fluorescent dye 1, 1, 2, 2-tetrakis[4-(3-methyl-1 H -benzimidazol-1-yl)phenyl ethylene tetraiodide (Tmbipe ) with aggregation-induced emission (AIE) potential was prepared and characterized. The presence of four positively charged methylated benzimidazole groups endowsTmbipe with excellent water solubility and almost undetectable background fluorescence. However, it can coordinate with two Hg 2+ ions or two organomercury molecules ( e.g. methylmercury and phenylmercury) to form a planar dinuclear Hg II tetracarbene complex, which can then self-aggregate to turn on AIE fluorescence. Such a fluorescence turn-on process can be completed in 3 min. In addition, synergic rigidification of the tetraphenylethylene-bridgedTmbipe molecule by mercury-mediated chelate ring formation and subsequent aggregation results in obviously higher fluorescence enhancement than that given by the single aggregation-induced one. Low background, high fluorescence enhancement and rapid response time makeTmbipe a good fluorescent probe for reliable, sensitive and highly selective quantitation of both inorganic and organic mercury species. This probe was also demonstrated to work well for identification of mercury species accumulation in living cells.