Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs. Issue 13 (1st March 2019)

• Record Type: Journal Article
• Authors: Zhang, Zhikun; Bai, Lichen; Hu, Xile
• Is Part Of: Chemical science. Volume 10:Issue 13(2019)
• Page Start: 3791
• Page End: 3795
• Publication Date: 2019-03-01
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c9sc00126c
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : Easily-assembled Ni MOFs are efficient and robust catalysts for alkene hydrosilylation. Abstract : We report the first Ni MOF catalysts for anti-Markovnikov hydrosilylation of alkenes. These catalysts are bench-stable and easily-assembled from simple Ni salts and carboxylic acids. The best catalyst gives turnover numbers up to 9500 and is robust even after 10 recycling runs. The catalyst can be applied for the hydrosilylation of a wide range of alkenes, achieving good synthetic utility and functional group tolerance.