Pyridine‐Fused Bis(Norcorrole) through Hantzsch‐Type Cyclization: Enhancement of Antiaromaticity by an Aromatic Bridge. (31st July 2017)
- Record Type:
- Journal Article
- Title:
- Pyridine‐Fused Bis(Norcorrole) through Hantzsch‐Type Cyclization: Enhancement of Antiaromaticity by an Aromatic Bridge. (31st July 2017)
- Main Title:
- Pyridine‐Fused Bis(Norcorrole) through Hantzsch‐Type Cyclization: Enhancement of Antiaromaticity by an Aromatic Bridge
- Authors:
- Li, Xiaofang
Meng, Yankui
Yi, Pinggui
Stępień, Marcin
Chmielewski, Piotr J. - Abstract:
- Abstract: A non‐catalytic condensation of Ni II β‐aminonorcorrole with aryl aldehydes is shown to produce a family of pyrromethane dimers that undergo deaminative cyclization to yield pyridine‐fused bis(norcorrole)s comprising two antiaromatic macrocycles communicating by an aromatic moiety. The new compounds were characterized by spectroscopic, structural, and electrochemical methods supported by DFT calculations, all of which revealed unexpected antiaromaticity enhancement in the fused system.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 36(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 36(2017)
- Issue Display:
- Volume 129, Issue 36 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 36
- Issue Sort Value:
- 2017-0129-0036-0000
- Page Start:
- 10950
- Page End:
- 10954
- Publication Date:
- 2017-07-31
- Subjects:
- Antiaromatizität -- Dimerisierungen -- Kondensierte Ringe -- Norcorrole -- Porphyrinoide
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201705715 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9920.xml