Systematic study on hybrid supercapacitor of Ni-Co layered double hydroxide//activated carbons. (10th May 2019)

• Record Type: Journal Article
• Authors: Qin, Qingqing; Ou, Dawei; Ye, Changjing; Chen, Lingxue; Lan, Binbin; Yan, Jian; Wu, Yucheng
• Is Part Of: Electrochimica acta. Volume 305(2019)
• Page Start: 403
• Page End: 415
• Publication Date: 2019-05-10
• Subjects: Hybrid supercapacitor -- Ni-Co layered double hydroxide -- Mass ratio -- Electrochemical potential window -- Cell design; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2019.03.082
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: Hybrid supercapacitors (HSCs) with high energy density have caused great interest. However, it is still lack of general principle to optimize the electrochemical performance. Hereby, an insightful study on HSCs has been carried out using devices based on flower-like NiCo layered double hydroxide (NiCo-LDH, 777 C g −1 ) and activated carbon (AC) in KOH. It has been found that the upper potential limit of NiCo-LDH is about 0.5 V (vs Ag/AgCl) while the lower potential limit of AC is about −1.1 V to −1.3 V. The stable potential window of HSC is 1.6 V. The key to boost cell specific capacitance is to enlarge the potential window of AC by adjusting the Zero Voltage through tuning the mass ratio between the two electrodes. The optimized mass ratio is found to be lower than that calculated by traditional method. We have developed a model to disclose the effect of materials performance, cell potential window and mass ratio on the cell performance. A parameter of match-coefficient (0.8–0.85, in our case) is proposed to estimate the optimized mass ratio. Following the optimized cell parameters, a demo of all-solid-state HSC (optimized mass ratio of 2) has been assembled using solid polymer electrolyte. It exhibits a high specific energy of 69.5 Wh kg −1 at 450 W kg −1 and good cycling stability with 95.7% capacitance retention after 5000 cycles within 1.8 V. This work sheds light on comprehensive understanding towards design and fabrication high performance HSCs. Graphical abstract: Model for the hybrid cell based on NiCo LDH//AC (left) and the prediction of normalized cell specific capacitance based on mass ratio and capacity ratio (right), and the inset is FESEM images of NiCo LDH nano-flowers.Image 1 Highlights: Flower-like NiCo-LDH with good performance were prepared. Principles for cell designing are revealed by two electrodes cell study. A model is developed to reveal the cell performance of HSCs. Match coefficient is proposed to estimate the optimized electrodes mass ratio. Stable all-solid-state HSC exhibits a high specific energy of 69.5 Wh kg −1 .