Ionic-to-electronic current amplification in hybrid perovskite solar cells: ionically gated transistor-interface circuit model explains hysteresis and impedance of mixed conducting devices. Issue 4 (19th March 2019)

• Record Type: Journal Article
• Authors: Moia, Davide; Gelmetti, Ilario; Calado, Phil; Fisher, William; Stringer, Michael; Game, Onkar; Hu, Yinghong; Docampo, Pablo; Lidzey, David; Palomares, Emilio; Nelson, Jenny; Barnes, Piers R. F.
• Is Part Of: Energy & environmental science. Volume 12:Issue 4(2019)
• Page Start: 1296
• Page End: 1308
• Publication Date: 2019-03-19
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/c8ee02362j
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : Interfacial-transistor circuit model couples electronic charge transfer to mobile ions. Abstract : Mobile ions in hybrid perovskite semiconductors introduce a new degree of freedom to electronic devices suggesting applications beyond photovoltaics. An intuitive device model describing the interplay between ionic and electronic charge transfer is needed to unlock the full potential of the technology. We describe the perovskite-contact interfaces as transistors which couple ionic charge redistribution to energetic barriers controlling electronic injection and recombination. This reveals an amplification factor between the out of phase electronic current and the ionic current. Our findings suggest a strategy to design thin film electronic components with large, tuneable, capacitor-like and inductor-like characteristics. The resulting simple equivalent circuit model, which we verified with time-dependent drift-diffusion simulations of measured impedance spectra, allows a general description and interpretation of perovskite solar cell behaviour.