Controllable synthesis of aluminum doped peony-like α-Ni(OH)2 with ultrahigh rate capability for asymmetric supercapacitors. Issue 18 (2nd April 2019)

• Record Type: Journal Article
• Authors: Wei, Jinying; Qiu, Daping; Li, Min; Xie, Zhenyu; Gao, Ang; Liu, Hongru; Yin, Suhong; Yang, Dongsheng; Yang, Ru
• Is Part Of: RSC advances. Volume 9:Issue 18(2019)
• Page Start: 10237
• Page End: 10244
• Publication Date: 2019-04-02
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c9ra00883g
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Ion substitution and micromorphology control are two efficient strategies to ameliorate the electrochemical performance of supercapacitors electrode materials. Abstract : Ion substitution and micromorphology control are two efficient strategies to ameliorate the electrochemical performance of supercapacitors electrode materials. Here, Al 3+ doped α-Ni(OH)2 with peony-like morphology and porous structure has been successfully synthesized through a facile one-pot hydrothermal process. The Al 3+ doped α-Ni(OH)2 electrode shows an ultrahigh specific capacitance of 1750 F g −1 at 1 A g −1, and an outstanding electrochemical stability of 72% after running 2000 cycles. In addition, the Al 3+ doped α-Ni(OH)2 electrode demonstrates an excellent rate capability (92% retention at 10 A g −1 ). Furthermore, by using this unique Al 3+ doped α-Ni(OH)2 as the positive electrode and a hierarchical porous carbon (HPC) as the negative electrode, the assembled asymmetric supercapacitor can demonstrate a high energy/power density (49.6 W h kg −1 and 14 kW kg −1 ). This work proves that synthesizing an Al 3+ doped structure is an effective means to improve the electrochemical properties of α-Ni(OH)2 . This scheme could be extended to other transition metal hydroxides to enhance their electrochemical performance.