Achieving high discharge energy density and efficiency with NBT-based ceramics for application in capacitors. Issue 14 (14th March 2019)

• Record Type: Journal Article
• Authors: Pan, Zhongbin; Hu, Di; Zhang, Yang; Liu, Jinjun; Shen, Bo; Zhai, Jiwei
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 14(2019)
• Page Start: 4072
• Page End: 4078
• Publication Date: 2019-03-14
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c9tc00087a
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : The 0.94(BNT–BST)–0.06KNN ceramic possesses an excellent stored energy storage density ( W s = ∼3.13 J cm −3 ), a recoverable energy storage density ( W r = ∼2.65 J cm −3 ), and maintains a relatively high efficiency ( η ∼ 84.6%). Abstract : High-performance capacitors, which have high energy storage density as well as high discharge efficiency, are desired. In this study, we have designed and prepared novel and high quality (1 − x )(0.65Bi0.5 Na0.5 TiO3 –0.35Bi0.1 Sr0.85 TiO3 )– x (K0.5 Na0.5 NbO3 ) [(1 − x )(BNT–BST)– x KNN, x = 0, 0.04, 0.06, 0.08, and 0.10] ceramics that demonstrated a remarkable energy storage capability, high efficiency, and ultrafast discharge speed. Particularly, the 0.94(BNT–BST)–0.06KNN ceramic possessed an excellent stored energy storage density ( W s = ∼3.13 J cm −3 ) and recoverable energy storage density ( W r = ∼2.65 J cm −3 ), and maintained a relatively high efficiency ( η = ∼84.6%) at a relatively low electric field of 180 MV m −1, which is superior to those of the lead-free BNT-based energy-storage materials. Moreover, excellent temperature (20–120 °C) and frequency (1–100 Hz) stabilities of the 0.94(BNT–BST)–0.06KNN ceramic were also achieved. More importantly, the 0.94(BNT–BST)–0.06KNN ceramic exhibited an ultrafast discharge rate ( τ 0.9 = ∼1.01 μs), a high level of discharge energy density ( W d −1.21 J cm −3 ), and excellent reliability in energy storage performance by consecutive cycling. Moreover, this study also provides an effective approach to attain large energy-storage capability along with high efficiency in BNT-based ceramics for application in pulsed power capacitors.