Pd–Ni Bimetallic Nanoparticles Supported on Zro2 as an Efficient Catalyst for Suzuki–Miyaura Reactions. (August 2018)

• Record Type: Journal Article
• Authors: Zhang, Li-Jie; Yao, Xian; Sun, Ying-xin; Zhang, Jia-wei; Cai, Chun
• Is Part Of: Journal of chemical research. Volume 42:Number 8(2018)
• Page Start: 419
• Page End: 423
• Publication Date: 2018-08
• Subjects: heterogeneous catalysis -- alloys -- nanochemistry -- bimetallic nanoparticles -- Suzuki–Miyaura coupling; Chemistry -- Research -- Periodicals; Chemistry -- Periodicals; 540.5
• DOI: 10.3184/174751918X15337409427516
• Languages: English
• ISSNs: 1747-5198

Abstract

Pd–Ni bimetallic nanoparticles (BMNPs) supported on ZrO2 were prepared by an impregnation–reduction method. The BMNPs showed excellent catalytic performance in Suzuki carbon–carbon cross-coupling reactions and almost quantitative conversion of the substrates was obtained under mild conditions in the absence of ligand. The excellent catalytic performance of the bimetallic catalyst could be a result of the synergistic effect between the two metal components. The catalyst showed outstanding recyclability during the reaction process; no obvious decrease in catalytic performance was observed after five cycles.