Efficient Heterogeneous Copper-Catalysed C–Se Coupling of Aryl Iodides with Symmetrical Diselenides towards Unsymmetrical Monoselenides. (November 2018)

• Record Type: Journal Article
• Authors: Zhao, Ruonan; Yan, Chenyu; Jiang, Yuanyuan; Cai, Mingzhong
• Is Part Of: Journal of chemical research. Volume 42:Number 11(2018)
• Page Start: 584
• Page End: 588
• Publication Date: 2018-11
• Subjects: copper -- C–Se coupling -- diaryl selenide -- MCM-41 -- heterogeneous catalysis; Chemistry -- Research -- Periodicals; Chemistry -- Periodicals; 540.5
• DOI: 10.3184/174751918X15409874473285
• Languages: English
• ISSNs: 1747-5198

Abstract

A highly efficient heterogeneous copper(I)-catalysed C–Se coupling of aryl iodides with diaryl diselenides was achieved in dimethylformamide at 110 °C under neutral conditions by using a 10 mol% of bipyridine-functionalised MCM-41-supported copper(I) complex [bpy-MCM-41-CuI] as the catalyst and magnesium as the reductive reagent, yielding a variety of unsymmetrical diaryl selenides in good to excellent yields. This heterogeneous copper catalyst can be easily recovered by a simple filtration of the reaction solution and recycled at least seven times without significant loss of activity.