Ferrocene-Containing Acylhydrazone Receptors: Synthesis, Structures and Electrochemical Anion Recognition Characteristics. (August 2017)

• Record Type: Journal Article
• Authors: Li, Xia; Liu, Wei; Song, Maoping
• Is Part Of: Journal of chemical research. Volume 41:Number 8(2017)
• Page Start: 491
• Page End: 496
• Publication Date: 2017-08
• Subjects: ferrocene -- acylhydrazone -- quinolin-8-yloxy -- electrochemistry -- anion sensing; Chemistry -- Research -- Periodicals; Chemistry -- Periodicals; 540.5
• DOI: 10.3184/174751917X15017625991813
• Languages: English
• ISSNs: 1747-5198

Abstract

Ferrocene-containing redox receptors bearing the 2-(quinolin-8-yloxy)acetohydrazide (qa) moiety on one arm, [Fe(Cpqa)Cp], or two arms, [Fe(Cpqa)2 ], have been synthesised and the X-ray crystal structure of [Fe(Cpqa)2 ] determined. [Fe(Cpqa)2 ] can sense H2 PO − 4 both electrochemically and selectively even in the presence of a large excess of Cl − and ClO − 4 .