Mn (II) Complexes Based on Oligopyridines: Structure, Thermal Studies and Optical Band-Gap Determination. (March 2016)

• Record Type: Journal Article
• Authors: Alghool, Samir; Slebodnick, Carla
• Is Part Of: Journal of chemical research. Volume 40:Number 3(2016)
• Page Start: 182
• Page End: 187
• Publication Date: 2016-03
• Subjects: terpyridine -- pentacyanopropenide -- dipyridyl -- Mn(II) complexes -- band gap; Chemistry -- Research -- Periodicals; Chemistry -- Periodicals; 540.5
• DOI: 10.3184/174751916X14558218716443
• Languages: English
• ISSNs: 1747-5198

Abstract

Two cationic complexes [Mn(II)(terpy)2 ]·2(PCP) and [Mn(II)(dipy)3 ]·2(PCP) (terpy = 2, 2′:6′, 2″-terpyridine) (dipy = 2, 2-dipyridyl) (PCP = pentacyanopropenide) have been synthesised. Single crystal X-ray diffraction revealed that the PCP ligand acts as a counter ion. The thermal stability of these compounds was investigated. Optical absorption measurements show that the fundamental absorption edge obeys Tauc's relation for the allowed non-direct transition. The optical band gap (Eg) values equal ~2.7 eV for both complexes.