Revisiting Ag–π interactions with bis((pyrrol-2-yl)methylene)hydrazine: CC versus CN bond complexation. Issue 12 (7th March 2019)

• Record Type: Journal Article
• Authors: Baudron, Stéphane A.; Chevreau, Hubert
• Is Part Of: CrystEngComm. Volume 21:Issue 12(2019)
• Page Start: 1853
• Page End: 1856
• Publication Date: 2019-03-07
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c9ce00168a
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Crystallographic and theoretical investigations of the assembly of bis((pyrrol-2-yl)methylene)hydrazine with Ag(i ) salts suggest that, in the solid state, Ag–π interactions involve CC rather than CN pyrrolic bonds, in contrast with an earlier and unique report with this ligand. Abstract : Reinvestigation of the assembly of bis((pyrrol-2-yl)methylene)hydrazine with Ag(i ) salts suggests that, in the solid state, Ag–π interactions involve CC rather than CN pyrrolic bonds, in contrast with an earlier and unique report with this ligand.